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Serena Williams, Djokovic advance on Day 2 in Melbourne

Danielle Elliot

Serena WIlliams started her quest for a record sixth Australian Open title with a commanding first-round win on Tuesday.

Facing 20-year-old Alison Van Uytvanck, Williams needed just 21 minutes to take the first set. It was her first time facing Van Uytvanck – Williams admitted before the match that she didn't even know how to pronounce the Belgian's name. Williams stumbled slightly in the second set before prevailing, 6-0, 6-4.

Fellow American Madison Brengle pulled off the biggest upset of Day 2, as the unseeded youngster knocked out No. 13 Andrea Petkovic. Venus Williams, seeded 18th, defeated Maria-Teresa Torro-Flor, 6-2, 6-2.

Jelena Jankovic, seeded 15th, fell 6-1, 6-4 to unranked Timea Bacsinszky. It's the earliest Jankovic has ever been ousted from this tournament. In the final women's upset of the day, Camila Giorgi defeated fellow Italian Flavia Penetta, who was the 12th seed, 4-6, 6-2, 6-3.

No. 4 Petra Kvitova, No. 8 Carolina Wozniacki, No. 6 Agnieszka Radwanska, No. 11 Dominika Cibulkova, No. 20 Sam Stosur, and Victoria Azarenka also advanced. Wozniacki and Azarenka will face off in the second round.

On the men's side, four-time Australian Open champion Novak Djokovic faced off against Grand Slam newcomer Aliaz Bedene. It's Djokovic's first tournament back since becoming a father in October. Bedene put up more of a fight than Djokovic seemed to expect, but the world No. 1 put the match away 6-3, 6-2, 6-4.

Stan Wawrinka is off to a quick start as he looks to defend his 2014 Australian Open title, advancing in straight sets in a dominating win over Marsel Ilhan. Kei Nishikori, who made a surprising run to the U.S. Open final in August, is also moving on after defeating Nicolas Almagro 6-4, 7-6, 6-2.

No. 8 Milos Raonic, No, 18 Gilles Simon and No. 19 John Isner also advanced in straight sets. American Denis Kudla nearly upset No. 12 Feliciano Lopez, forcing three match points, but failed to convert. Lopez is moving on with the 3-6, 6-2, 4-6, 6-2, 10-8 victory.