The Champions League finalist begins its campaign this term with a trip to the San Paolo and the 46-year-old is full of respect for his club's opponent.
"Napoli play a very lively kind of football, it's not too different from ours," Klopp told reporters. "If you look at the players at Napoli, they have a very experienced defense while their attack stands for pace and technique.
"We do not fear them, but we know what we are dealing with and have a lot of respect."
The Italian side had a busy summer in the transfer market, bringing in the likes of Gonzalo Higuain, Pepe Reina, Raul Albiol and Jose Callejon.
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